Comic Book First Appearances - Villains

Abomination Tales to Astonish #90, 4/67

Abra Kadabra Flash #128, 2/62

Absorbing Man Journey Into Mystery #114, 3/65

Amazo The Android Brave & The Bold #30, 6-7/60

Angle Man Wonder Woman #70, 11/54

Annihilus Fantastic Four Annual #6, 11/68

Apocalypse (cameo) X-Factor #5, 6/86; (full app.) X-Factor #6, 7/86

Arcade Marvel Team-Up #66, 2/78

Atomic Skull Superman #323, 5/78; (modern) Action Comics #670, 10/91

Attuma Fantastic Four #33, 12/64

Bane Batman: Vengeance of Bane Special #1, '92

Banshee X-Men #28, 1/67

Baron Blood Invaders #7, 7/76

Baron Mordo Strange Tales #111, 8/63

Baron Strucker Sgt. Fury #5, 1963

Baron Zemo Captain America #276

Batmite Detective #267, 5/59

Batroc Tales of Suspense #76, 4/66

Beetle Strange Tales #123, 8/64

Bengal Daredevil #258, 9/88

Beyonder Marvel Two-In-One #63, 1986

Big Man Amazing Spider-Man #10, 3/64

Bizarro Superboy #68, 10-11/56

Bizarro Batman World's Finest Comics #156

Bizarro Flash Superman's Girlfriend Lois Lane #74, 5/67

Bizarro Krypto Superboy #82, 1960

Bizarro Lana Lang Adventure Comics #292, 1/62

Bizarro Lucy Lane Adventure Comics #292, 1/62

Bizarro Lex Luthor Adventure Comics #293, 2/62

Bizarro Lois Lane Action Comics #255, 8/59

Bizarro Mxyzptlk Adventure Comics #286, 7/61

Bizarro Supergirl Superman #140, 10/60

Bizarro Titano Adventure Comics #295, 4/62

Black Cat Amazing Spider-Man #194, 7/79

Black Mask Batman #386, 8/85

Blackout Ghost Rider #2, 6/90

Black Racer New Gods #3, 6-7/71

Black Spider Detective Comics #463

Blastarr Fantastic Four #62, 5/67

Blizzard Iron Man #86, 1976

Blob X-Men #3, 1/64

Blockbuster Detective Comics #345, 11/65

Boomerang Tales to Astonish #81, 7/66

Brain Storm Justice League of America #32, 12/64

Brain Wave All Star Comics #15, 2-3/43

Brainiac Action Comics #242, 7/58; (modern) Adventures of Superman #438, 2/88

Brainwasher (Kingpin) Amazing Spider-Man #59, 4/68

Brother Blood New Teen Titans #21, 7/82

Brother Voodoo Strange Tales #169, 9/73

Bullet Daredevil #250, 12/88

Bullseye Nick Fury Agent of Shield #15, 11/69

Calypso Amazing Spider-Man #209, 10/80

Captain Boomerang Flash #117, 12/60

Captain Cold Showcase #8, 5-6/57

Captain Fear Adventure Comics #425, 12-1/72-73

Captain Nazi Master Comics #21, 12/41

Cardinal New Warriors #28, 10/92

Carnage (1st full app.) Amazing Spider-Man #361, 4/92; (cameo) Amazing Spider-Man #360, 3/92

Carrion Spectacular Spider-Man #25, 12/78

Cat-Man Detective Comics #311, 1/63

Catwoman (1st in costume) Batman #3, Fall '40; (1st time called Catwoman) Batman #2, Sum '40; (modern, Selina Kyle) Batman #404, 2/87; (new costume w/o cat-head mask) Batman #35, 5-6/46; (new) Detective Comics #624, 12/90; (S.A.) Superman's Girlfriend Lois Lane #70, 11/66; (The Cat) Batman #1, Spr '40

Cavalier Detective Comics #81, 11/43

Chameleon Amazing Spider-Man #1, 3/63

Changeling X-Men #35, 8/67

Cheetah Wonder Woman #6, Fall '43; (new) (cameo) Wonder Woman #274, 12/80; (new) (full app.) Wonder Woman #275, 1/81

Chronos Atom #3, 10-11/62

Chunk Flash #9, 2/88

Claw Silver Streak Comics #1, 12/39

Clayface I (Basil Karlo) Detective Comics #40, 6/40

Clayface II (Matt Hagen) Detective Comics #298, 12/61

Clayface III (Preston Payne) Detective Comics #478, 7-8/78

Clock King World's Finest Comics #111, 8/60

Clown Flash #270, 2/79

Colonel Computron Flash #304, 12/81

Composite Superman World's Finest #142

Computo Adventure Comics #340, 1/66

Constrictor Incredible Hulk #212, 6/77

Copperhead Daredevil #124, 6/75

Crime Master Amazing Spider-Man #26, 7/65

Crimson Dynamo (Anton Vanko) Tales of Suspense #46, 10/63

Crimson Dynamo II (Boris Turgenov) Tales of Suspense #52, 4/64

Crimson Dynamo III (Alex Nevsky) Iron Man #21, 3/78

Crimson Dynamo IV (Yuri Petrovich) Champions #8, 10/76

Crimson Dynamo V (Dimitri Bukharin) Iron Man #109, 4/78

Cyborg (Superman impersonator) Adventures of Superman #466, 5/90

Cyclone Amazing Spider-Man #143, 4/75

Dark Phoenix X-Men #134

Darkseid (1st full app.) Forever People #1, 2-3/71; (cameo) Superman's Pal Jimmy Olsen #134, 12/70

Deadshot Batman #59, 6-7/50; (1st modern app.) Detective Comics #474, 11-12/77

Death's Head Daredevil #56, 9/69

Deathstalker (formerly Death's Head) Daredevil #114, 7/74

Demogoblin Web of Spider-Man #86, 3/92

Despero Justice League of America #1, 10-11/60

Destroyer Journey Into Mystery #118, 7/65

Dev-Em, the Knave from Krypton Adventure Comics #287, 8/61

Diablo Fantastic Four #30, 9/64

Doctor Destiny Justice League of America #5, 6-7/61

Doctor Doom Fantastic Four #5, 6/62

Doctor Light I Justice League of America #12, 6/62

Doctor Light II Crisis on Infinite Earths #4, 6/85

Doctor Octopus Amazing Spider-Man #3, 6/63

Doctor Polaris Green Lantern #21, 6/63

Doctor Regulus Adventure Comics #348, 9/66

Doom 2099 Marvel Comics Presents #118, '92

Doomsday (cameo) Superman: The Man of Steel #17, 11/92; (full app.) Superman: The Man of Steel #18, 12/92

Dormammu Strange Tales #126, 11/64

Dr. Death (modern) Batman #345, 3/82

Dr. Doom Fantastic Four #5, 6/62

Dr. Double X Detective Comics #261, 11/58

Dr Light Justice League of America #12, '62

Dr. Octopus Amazing Spider-Man #3, 5/63

Dr. Phosphorous Detective Comics #469

Dr. Psycho Wonder Woman #5, 6-7/43

Dr. Spectro Captain Atom #78, 12/65; (new) Captain Atom #6, 8/87; (1st DC app.) Crisis on Infinite Earths #9, 12/85

Dragon Man Fantastic Four #35, 2/65

Drax the Destroyer (re-intro) (cameo) Silver Surfer #35, 3/90; (re-intro) (full app.) Silver Surfer #37, 5/90

Dreadknight Iron Man #101, 8/77

Dragon Man Fantastic Four #35, 2/65

Dummy (Vigilante villain) Leading Comics #1, Win '41-42

Electro Amazing Spider-Man #9, 2/64

Enchantress Journey Into Mystery #103, 4/64

Enchantress Strange Adventures #187

Enforcer Ghost Rider #22, 1977

Evil Star Green Lantern #37, 7/65

Exterminator (becomes Death-Stalker) Daredevil #39, 4/68

Fatal Five Adventure Comics #352, 1/67

Fatman Batman #113, 2/58

Felix Faust Justice League of America #10, 3/62

Fiddler All-Flash #32, 12-1/47-48

Fin Fang Foom Strange Tales #89, 10/61

Firelord Thor #225

Foolkiller (1st) Man-Thing #3, 3/74

Foolkiller II (Greg Salinger) (cameo) Omega the Unknown #8, 5/77; (Greg Salinger) (full app.) Omega the Unknown #9, 7/77

Galactus Fantastic Four #48, 3/66

Gambler Green Lantern #12, Sum '44

Gamora Strange Tales #180, 6/75; (re-intro) Silver Surfer #46, 2/91

Gentleman Ghost (modern) Batman #310, 4/79

Gibbon Amazing Spider-Man #110, 7/72

Gladiator Daredevil #18, 7/66

Golden Glider Flash #250, 6/77

Gorgon Fantastic Four #44, 11/65

Gorilla Grodd, the Super Gorilla Flash #106, 4-5/59

Green Goblin I (Norman Osborn) Amazing Spider-Man #14, 7/64

Green Goblin II (Harry Osborn) Amazing Spider-Man #136, 9/74

Grey Gargoyle Journey Into Mystery #107, 8/64

Grim Reaper Avengers #52, 5/68

Grizzly Amazing Spider-Man #139, 12/74

Hammerhead Amazing Spider-Man #113, 10/72

Harlequin All-American Comics #89, 9/47

Hate Monger Fantastic Four #21, 12/63

Havoc (not in costume) X-Men #56; (in costume) #58

Heat Wave Flash #140, 6/63

Hector Hammond Green Lantern #5, 3-4/61

Hela Journey Into Mystery #102, 3/64

High Evolutionary Thor #134, 11/66

Hobgoblin (new) (Macendale) Spectacular Spider-Man #147, 2/89

Hobgoblin I (Ned Leeds) Amazing Spider-Man #238, 3/83

Hobgoblin II (Macendale/Jack O'Lantern) Amazing Spider-Man #289, 6/87

Hugo Strange (1st modern app.) Detective Comics #470, 3-4/77

Human Cobra Journey Into Mystery #98, 11/63

Human Top (Whirlwind) Tales to Astonish #50, 12/63

Humbug Web of Spider-Man #19, 10/86

Hydro Man Amazing Spider-Man #212, 12/81

Hyena Firestorm #4, 8-9/78

Icicle All-American Comics #90, 10/47

Insect Queen (Lana Lang) Superboy #124, 10/65

Iron Jaw Boy Comics #3, 4/42

Jack O'Lantern (Macendale) Machine Man #19, 2/81; (new) Captain America #396, 1/92

Jackal Amazing Spider-Man #129, 2/74

Jester Daredevil #42 ,7/68

Jigsaw Amazing Spider-Man #188, 1/79

Joker Batman #1, Spr '40

Joker's Daughter Batman Family #6, 7-8/76

Juggernaut X-Men #12, 7/65

Kang Avengers #8, 9/64

Kanjar Ro Justice League of America #3, 2-3/61

Key, The Justice League of America #41, 12/65

Killer Croc Batman #357, 3/83

Killer Shark Blackhawk #50, 3/52

Kingpin Amazing Spider-Man #50, 7/67

Klaw Fantastic Four #53, 8/66

Kraven the Hunter Amazing Spider-Man #15, 8/64

Kurgo Fantastic Four #7, 10/62

Leader Tales to Astonish #62, 12/64

Legion of Super Villains Superman #147, 8/61

Lex Luthor (bald) Superman #10, 5-6/41; (new) Man of Steel #4, 12/86; (red hair) Action Comics #23, 5/40; (Silver Age) Adventure Comics #271, 4/60

Lightmaster Spectacular Spider-Man #3, 2/77

Living Monolith X-Men #56

Lizard Amazing Spider-Man #6, 11/63

Loki Journey Into Mystery #85, 10/62

Looter Amazing Spider-Man #36, 5/66

Lord Shilling (Tomahawk foe) Tomahawk #28, 11/54

Lunatik (1st full app.) Defenders #56, 2/78; (cameo) Defenders #53, 11/77

Mad Hatter Batman #49, 10-11/48; Detective Comics #230, 4/56

Mad Thinker Fantastic Four #15, 6/63

Madame Medusa Fantastic Four #36, 3/65

Maelstrom Marvel Two-In-One #71, 1/81

Magica de Spell Uncle Scrooge #36, 12/62

Magneto X-Men #1, 9/63

Magpie (new) Man of Steel #3, 11/86

Magus Strange Tales #178, 2/75; (re-intro) Warlock and the Infinity Watch #7, 8/92

Malevolence (Mephisto's daugh ter) Guardians of the Galaxy #7, 12/90

Man-Ape Avengers #62

Man-Bat Detective Comics #400, 6/70

Man-Wolf Amazing Spider-Man #124, 9/73

Mandarin Tales of Suspense #50, 2/64

Manhunters 1st Issue Special #5, 8/75

Mephisto Silver Surfer #3, 12/68

Metallo (Jor-El's robot) (1st app.) Superboy #49, 6/56; (new) Superman #310, 4/77; (new) Superman #1, 1/87; (re-intro) Action Comics #252, 5/59; (re-intro, 3rd app.) Adventure Comics #276, 9/60

Microwave Man Action Comics #487, 9/78

Mime Batman #412, 10/87

Mimic X-Men #19, 4/66

Mirror Master Flash #105, 2-3/59

Mist Adventure Comics #67, 10/41

Mister Element Showcase #13, 3-4/58

Mister Sinister X-Men #221

Modok Tales of Suspense #94, 10/67

Modred the Mystic (re-intro) Darkhold #3, 12/92

Mole Man Fantastic Four #1, 11/61

Molecule Man Fantastic Four #20, 11/63

Molten Man Amazing Spider-Man #28, 9/65

Morbius the Living Vampire Amazing Spider-Man #101, 10/71

Mordru Adventure Comics #369, 6/68

Mortan (Adam Strange foe) Mystery In Space #62

Mr. Atom Captain Marvel Adventures #78, 11/47

Mr. Baffle Detective Comics #63, 5/42

Mr. Freeze Batman #121, 2/59

Mr. Hyde Journey Into Mystery #99,12/63

Mr. Mind Captain Marvel Adventures #22, 3/43; (re-intro) Shazam! #2, 4/73

Mr. Mxyzptlk Superman #131, 8/59; (new) Superman #11, 11/87; Superman #30, 10/44

Mr. Tawny Captain Marvel Adventures #79, 12/47

Multi-Man Challengers of the Unknown #14, 12-1/59-60

Mysterio Amazing Spider-Man #13, 6/64

Nightmare Strange Tales #110, 7/63

Nightshade Captain America #164, 8/73

Nitro Captain Marvel #34, 9/74

Ocean Master Aquaman #29

Outsider Detective Comics #334, 12/64

Owl Daredevil #3, 8/64

Paladin Daredevil #150, 2/78

Parasite Action Comics #340, 8/66; Fury of Firestorm #58, 4/87

Peg-leg Pete Mickey Mouse #3, 1933

Penguin Detective Comics #58, 12/41; (S.A.) Batman #155, 4/63

Pied Piper Flash #106, 4-5/59

Pieface Green Lantern #2, 9-10/60

Plant-Master Atom #1, 6-7/62

Plunderer Daredevil #12, 1/66

Poison Ivy Batman #181, 6/66

Porcupine Tales To Astonish #48, 10/63

Prankster Action Comics #51, 8/42

Princess Python Amazing Spider-Man #22, 3/65

Professor Amos Fortune Justice League of America #6, 8-9/61

Professor Zoom Flash #139, 1963

Prowler Amazing Spider-Man #78, 11/69

Psycho Pirate All Star Comics #23, Win '44-45

Psycho-Man Fantastic Four Annual #5, 11/67

Puma Amazing Spider-Man #256, 9/84

Punisher Amazing Spider-Man #129, 2/74

Puppet Master Batman #3, Fall '40; Fantastic Four #8, 11/62

Rainbow Raider Flash #286, 6/80

Rama-Tut Fantastic Four #19, 10/63

Rampage Superman #7, 7/87

Rancor (1st full app.) Guardians of the Galaxy #9, 2/91; (cameo) (descendant of Wolverine) Guardians of the Galaxy #8, 1/91

Ras Al Ghul Batman #232, 7/71

Reaper Batman #237, 12/71

Red Ghost Fantastic Four #13, 4/63

Red Skull Captain America Comics #1, 3/41; (S.A.) Tales of Suspense #65, 5/65

Rhino Amazing Spider-Man #41, 10/66

Riddler Detective Comics #140, 10/48; (S.A.) Batman #171, 5/65

Ringmaster Incredible Hulk #3, 9/62

Rose Amazing Spider-Man #253, 6/84

Rose and the Thorn Flash Comics #89, 11/47; (new) Superman's Girlfriend Lois Lane #105

Saber-Tooth Flash #291, 11/80

Sabretooth Iron Fist #14, 8/77

Sandman Amazing Spider-Man #4, 9/63

Sandstorm Web of Spider-Man #107, 12/93

Sargon (re-intro) Flash #186, 8/69

Sargon the Sorcerer (1st story app.) All-American Comics #26, 5/41; (text only) All-American Comics #24, 3/41

Sauron X-Men #60

Scarecrow Tales of Suspense #51, 3/64; World's Finest Comics #3, Fall '41; Dead of Night #11, 8/75; (S.A.) Batman #189, 1967

Schemer Amazing Spider-Man #83, 4/70

Scorpion Amazing Spider-Man #20, 1/65

Serpent Crown Sub-Mariner #9, 1/69

Sha-Shan Amazing Spider-Man #108, 5/72

Shade (modern) Flash #298, 6/81

Shadow Thief Brave and the Bold #36,6-7/61

Shaper Incredible Hulk #155, 9/72

Shark Amazing-Man Comics #6, 10/39; Green Lantern #24, 10/63

Shocker Amazing Spider-Man #46, 3/67

Shotgun Daredevil #272, 9/89

Shroud Super-Villain Team-Up #5, 4/76

Signalman Batman #112, 12/57; (S.A.) Detective Comics #466

Silver Banshee Action Comics #495, 12/87

Silvermane Amazing Spider-Man #73, 6/69

Silver Samurai Daredevil #111, 6/74

Sinestro Green Lantern #7, 7-8/61

Sivana Whiz Comics #1, 2/40

Sivana, Jr. Captain Marvel Adventures #52, 1/46

Sky Pirate Green Lantern #27, 8-9/47

Solarr Captain America #160, 4/73

Solo Web of Spider-Man #19, 10/86

Solomon Grundy All-American Comics #61, 11/44; (S.A.) Showcase #55, 3-4/65

Sonar Green Lantern #14, 7/62

Sorcerer Alpha Flight #71, 5/89

Speed McGee Flash #5, 10/87

Spirit of Vengeance (futuristic Ghost Rider) Guardians of the Galaxy #13, 6/91

Spyder New Mutants #68, 10/88

Star Thief Warlock #14, 10/76

Stilt-Man Daredevil #8, 6/65

Sting Ray Sub-Mariner #19, 11/69

Stranger X-Men #11, 5/65

Sub-Mariner (S.A) Fantastic Four #4, 5/62

Sunburst New Adventures of Superboy #45, 9/83

Super Skrull Fantastic Four #18, 9/63

Supremo Superboy #132, 1966

Swordsman Avengers #19, 8/65

Tantrum Night Thrasher: Four Control #2, 11/92

Tarantula Amazing Spider-Man #134, 7/74

Taskmaster Avengers #119, 1/80

Tattooed Man Green Lantern #23, 9/63

Terra-Man Superman #249, 4/72

Terrax Fantastic Four #211, 10/79

Terrible Tinkerer Amazing Spider-Man #2, 5/63

Thanos Iron Man #55, 2/73; (re-intro) (cameo) Silver Surfer #34, 2/90; (re-intro) (full app.) Silver Surfer #35, 3/90

Thinker All-Flash #12, Fall '43

Thundra Fantastic Four #129, 12/72

Tiger Shark (new) Namor, the Sub-Mariner #35, 2/93; (S.A.) Sub-Mariner #5, 9/68

Time Trapper Adventure Comics #321, 6/64

Titanium Man Tales of Suspense #69, 9/65

Titano Superman #127, 2/59

Toad X-Men #4, 3/64

Tombstone Web of Spider-Man #36, 3/88; (full app.) Spectacular Spider-Man #138, 5/88

Top Flash #122, 6-7/61

Torpedo Daredevil #126, 8/75

Toyman Action Comics #64, 9/43; (new) Superman #13, 1/88; (S.A.) Action Comics #432, 2/74

Trapster Strange Tales #104, 1/63

Trauma Incredible Hulk #394, 6/92

Trickster Flash #113, 6-7/60

Turtle Showcase #4, 9-10/56

Tweedledum & Tweedledee Detective Comics #74, 4/43

Two-Face Detective Comics #66, 8/42; (S.A) World's Finest #173, 1/68

Typhoid Mary Daredevil #254, 5/88

Ulik Thor #137

Ultron Avengers #54

Ulthoon (Adam Strange foe) Mystery In Space #61,

Umar Strange Tales #150, 11/66

Unicorn Tales of Suspense #56, 8/64

Universo Adventure Comics #349, 10/66

Unus the Untouchable X-Men #8, 11/64

U. S. Jones Wonderworld Comics #28, 8/41

Vandall Savage Green Lantern #10 ,Win '43; (S.A.) Flash #137, 1963

Vanisher X-Men #2, 11/63

Venom (1st full app.) Amazing Spider-Man #300, 5/88; (cameo w/costume) Amazing Spider-Man #298; (cameo, no costume), #299, 4/88

Vindicator X-Men #109, 5/78

Viper Captain America #110, 2/69

Vulture Amazing Spider-Man #2, 5/63

Warpath X-Men #193, 5/85

Watcher Fantastic Four #13, 4/63

Weapon Omega Alpha Flight #102, 11/81

Weather Wizard Flash #110, 12-1/59-60

Whirlwind (Human Top) Tales to Astonish #50, 12/63

White Queen X-Men #132, 4/80

Wizard Strange Tales #102, 11/62

Zemo Avengers #6, 7/64

Zzzax Incredible Hulk #166, 8/73